By Jean-Paul Duroudier
Adsorption-Dryers for Divided Solids, a part of the commercial gear for Chemical Engineering set, presents sensible functions and distinctive wisdom on international learn, offering an in-depth examine of a number of points in the box of chemical engineering.
This quantity discusses the primary of adsorption of gaseous impurities, sensible facts on adsorption, ion alternate and chromatography, the idea of drying, and the idea of imbibition. the writer additionally presents equipment wanted for realizing the gear utilized in utilized thermodynamics within the desire of encouraging scholars and engineers to construct their very own courses. Chapters are complemented with appendices which supply additional info and linked references.
- Provides key features of fluid-solid equilibriums
- Includes a pragmatic use of adsorbents that may be utilized
- Covers specific circumstances in chromatography
- Presents normal equipment for calculations on dryers
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Additional resources for Adsorption-Dryers for Divided Solids
Consider two solutes such that A is adsorbed less than B. If the two solutes A and B have a Langmuirian isotherm, at the end of the band of A, the concentrations cA and qA decrease, and the equilibrium Adsorption and Ion-exchange Chromatography 29 coefficient (dq/dc)A increases, so that gradient may become equal to the value (dq/dc)B and, therefore, we may see a mixture of bands A and B. This phenomenon limits the usefulness of the pusher method. One possible solution is, in advance, to adsorb the product A to the solid in a very small quantity before carrying out the adsorption-pushing operation.
WIL 66] proposed a method for calculating the transfer coefficient across the liquid film, but Guiochon et al. s-1. 3. (Balance) equation for the fluid We have two equations: one for the fluid and the other for the solid particles. Let us begin with the fluid. The concentration c of the solute in the fluid varies over time with the velocity dc/dt in each segment of the column, of thickness ∆z. m−3; z: length along the column: m; Adsorption and Ion-exchange Chromatography 35 The concentration expressed per m3 of the column is εc; Da: axial dispersion coefficient along the column.
E. everywhere) between the fluid and the solid. 2. Constant concentration lines in the fluid We shall set: F= 1− ε ε The material balance becomes: ∂ci dc (1 + Ff ') + u i = 0 ∂t ∂z As shown in Appendix 2, for a closed-loop derivation, we can write: ∂c ∂t ∂c = × ∂z t ∂z c ∂t z Let us eliminate (1 + Ff ') ∂c between this equation and the material balance. ∂z ∂c ∂t ∂c =u ∂t z ∂z c ∂t z ∂c . We obtain the following for the speed of ∂t z progression of a wave of constant concentration: Let us simplify by ∂z u 1 = = =U 1 + Ff ' ( ∂t / ∂z )c ∂t c (Appendix 2: theorem of reciprocity) For an ideal system, the curves with c=const.